Increasing Mass Loading Through Improved
Slurry Dispersion
Achieving higher mass loading is one of the most effective ways to boost electrode energy density - but only if the slurry structure and coating behavior remain stable. Dispersants play a key role in enabling this balance by modifying slurry density, improving particle distribution, and supporting consistent electrochemical performance even at elevated loadings.
How Dispersants Enable Higher Mass Loading
Experimental observations show that increasing the dispersant dosage can directly modify the cast slurry density. This structural adjustment helps formulators pack more active material into the electrode without compromising uniformity or processability.
By improving dispersion, the slurry becomes more homogeneous, reducing particle clustering and creating a more efficient internal structure. This, in turn, allows manufacturers to safely increase the solids content - and ultimately the mass loading - while maintaining stable coating behavior.
Maintaining Electrochemical Performance at Higher Loadings
Any change in electrode density or internal structure will influence battery performance, which is why electrochemical validation is essential. Half‑cell coin cell tests demonstrate that the addition of dispersant not only maintains performance at higher loadings, but can actually improve it.
Enhanced Capacity Across Select C‑Rates
C‑rate testing shows that slurries containing dispersant deliver higher capacity at certain discharge rates compared to dispersant‑free formulations. This improvement is linked to:
- Better conductive path formation
- More uniform active‑material distribution
- Reduced agglomeration, enabling more efficient ion transport
These benefits are especially important at higher mass loadings, where maintaining accessibility and conductivity inside the electrode is more challenging.
Longer Cycle Life at Increased Density
Life‑cycle testing also reveals that electrodes prepared with dispersant show higher retained capacity over repeated cycles. Improved dispersion helps maintain mechanical and electrical integrity even as the electrode becomes denser, reducing degradation mechanisms such as particle detachment or disrupted conductive networks.
Mass Loading as a Performance Lever
As the industry pushes for higher energy density, increasing mass loading has become a critical strategy. However, high loading can only be successful if the electrode remains uniform, stable, and electrochemically active - and that depends heavily on how well the slurry is dispersed.
By optimizing dispersant dosage, manufacturers can:
- Increase solids content without sacrificing process stability
- Achieve more uniform, higher‑density electrodes
- Maintain or enhance capacity and rate performance
- Extend cycle life even at elevated loadings
In this way, dispersants function as a powerful enabler for next‑generation, high‑energy lithium‑ion electrodes, supporting higher mass loading without compromising quality.
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Read our Publication: "Debundling of SWCNTs using a Non-Toxic, Low Carbon Footprint Dispersant"
Abstract
A fully aqueous, N-methyl-2-pyrrolidone–free strategy for debundling single-walled carbon nanotubes (SWCNTs) is reported using the renewable dispersant Vanisperse® LI. Dispersions at 2 mg mL−1 were subjected to probe ultrasonication at 0.3 W mL−1 and evaluated using oscillatory rheology. Complex viscosity (η*) exhibited a transient maximum (~75 min) consistent with the formation of a percolated fibrous network, followed by a decline as debundling progressed. An optimum dispersant coverage of ~1.5 mg m−2 minimized η*, while overdosing likely induced multilayer adsorption and bridging seen by a rapid increase in η*. A two-stage centrifugation at 10,000× g yielded storage-stable suspensions of debundled SWCNTs without ultracentrifugation. SEM confirmed substantial debundling into thin fiber-like bundles. By formulating a dispersion with a dispersant that has a significantly lower cradle-to-gate carbon footprint than both fossil-based and bio-based alternatives such as CMC, this work presents a more sustainable approach to producing debundled SWCNT dispersions for advanced material applications.
Technical Bulletin: Dispersion of Carbon Nanotubes with Vanisperse LI
Borregaard’s bio-based battery additives are designed for use in water-based electrode slurries and to stabilize aqueous carbon nanotube (CNT) dispersions. Obtained from sustainably sourced wood, our products are non-toxic, environmentally friendly, and highly effective.
Vanisperse LI provides a uniquely sustainable alternative and affords a lower CO2 footprint than petroleum-derived additives. Efficient dispersion of CNTs is critical for achieving uniform electrode composition and optimal battery performance. Sustainable water-soluble dispersants are essential to de-agglomerate CNTs in water, preventing the hydrophobic carbons from reforming agglomerates.
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