De-agglomeration of conductive carbons

With Vanisperse LI

Silicon Anodes: the Next Generation of High‑Energy

Batteries

Silicon anodes are emerging as one of the most promising pathways to dramatically increase the energy density of next‑generation lithium‑ion and solid‑state batteries. As demand grows for longer‑range electric vehicles, faster‑charging consumer electronics, and more efficient energy storage, silicon is rapidly gaining attention across the global battery industry.

Why Silicon Anodes Matter

Conventional graphite anodes have nearly reached their theoretical limits for capacity, restricting further improvements in battery performance. Silicon, by contrast, offers a theoretical capacity up to nearly 10 times higher than graphite (up to ~3,579 mAh/g vs. 372 mAh/g), making it a strong candidate for high‑energy batteries. [ufinebattery.com]

Recent breakthroughs have accelerated the transition to silicon‑based anodes. Since 2024, production capacity has expanded in the US, South Korea, and China as manufacturers race to commercialize the technology.
Multiple companies—including Group14, NanoGraf, and Nexeon—are now scaling up, reporting material performance improvements of up to 50% higher energy density at commercial scale. [mitsui.com] [chargedevs.com]

The Remaining Challenges

Despite their potential, silicon anodes face persistent technical barriers, including:

  • Extreme volume expansion (up to 300%) during lithiation, which can crack electrodes and shorten cycle life
  • Instability at interfaces, especially in solid‑state battery systems
  • Processing challenges caused by silicon’s tendency to aggregate and destabilize slurries during electrode manufacture

These issues have driven the industry to explore new binders, conductive additives such as carbon nanotubes (CNTs), and better dispersion technologies. [mitsui.com]

Where Vanisperse LI Supports Silicon‑Anode Development

As silicon anodes become more widely adopted, slurry stability and uniformity become critical. High‑silicon or silicon‑carbon composite electrodes typically rely on a network of conductive additives—like SWCNTs—to maintain conductivity despite silicon’s expansion. But CNTs are notoriously difficult to disperse due to their hydrophobicity and tendency to form aggregates.

This is where Vanisperse LI, a bio‑based dispersant for CNT‑containing aqueous slurries, offers meaningful advantages:

1. Improved Electrical Pathway Stability

Silicon’s expansion can disrupt conductive pathways. Well‑dispersed SWCNTs help maintain a continuous conductive network. Vanisperse LI promotes de‑bundling and uniform dispersion of SWCNTs, supporting a more resilient electrode architecture. [mitsui.com]

2. Controlled Viscosity in High‑Solids Silicon Slurries

Silicon electrodes—especially high‑loading anodes—tend to produce slurries with high, nonlinear viscosity. Vanisperse LI reduces and stabilizes viscosity, improving mixability, pumpability, and coating consistency. [mitsui.com]

3. Reduced Risk of Particle Jamming During Coating

Large silicon particles combined with CNT bundles increase the risk of slot‑die defects and line stoppages. By preventing CNT reagglomeration and reducing particle size distribution, Vanisperse LI helps maintain smooth, defect‑free coating, even at elevated solids. [mitsui.com]

4. Enabling Higher Solids for Next‑Gen Anodes

Because Vanisperse LI stabilizes slurry flow, manufacturers gain the flexibility to increase silicon content or overall solids loading—a key path to improved energy density and reduced drying time.

Powering the Batteries of the Future

Whether in advanced lithium‑ion or emerging solid‑state systems, silicon‑based anodes are positioned to transform battery performance in the coming years. Their success, however, depends not only on material breakthroughs but also on achieving stable, scalable, and efficient electrode manufacturing.

Vanisperse™ LI supports this transition by enabling better dispersion of conductive additives, improving slurry stability, and enhancing process reliability—all essential as silicon anodes move from pilot lines to large‑scale production.

Read our PUBLICATION "DEBUNDLING OF SWCNTS USING A NON-TOXIC, LOW CARBON FOOTPRINT DISPERSANT"

Abstract

A fully aqueous, N-methyl-2-pyrrolidone–free strategy for debundling single-walled carbon nanotubes (SWCNTs) is reported using the renewable dispersant Vanisperse® LI. Dispersions at 2 mg mL−1 were subjected to probe ultrasonication at 0.3 W mL−1 and evaluated using oscillatory rheology. Complex viscosity (η*) exhibited a transient maximum (~75 min) consistent with the formation of a percolated fibrous network, followed by a decline as debundling progressed. An optimum dispersant coverage of ~1.5 mg m−2 minimized η*, while overdosing likely induced multilayer adsorption and bridging seen by a rapid increase in η*. A two-stage centrifugation at 10,000× g yielded storage-stable suspensions of debundled SWCNTs without ultracentrifugation. SEM confirmed substantial debundling into thin fiber-like bundles. By formulating a dispersion with a dispersant that has a significantly lower cradle-to-gate carbon footprint than both fossil-based and bio-based alternatives such as CMC, this work presents a more sustainable approach to producing debundled SWCNT dispersions for advanced material applications.

Click here to read the full article.

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Dispersion of Carbon Nanotubes with Vanisperse LI

Borregaard’s bio-based battery additives are designed for use in water-based electrode slurries and to stabilize aqueous carbon nanotube (CNT) dispersions. Obtained from sustainably sourced wood, our products are non-toxic, environmentally friendly, and highly effective. Vanisperse LI provides a uniquely sustainable alternative and affords a lower CO2 footprint than petroleum-derived additives. Efficient dispersion of CNTs is critical for achieving uniform electrode composition and optimal battery performance. Sustainable water-soluble dispersants are essential to de-agglomerate CNTs in water, preventing the hydrophobic carbons from reforming agglomerates. 


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